No cornstarch? Use 2 tbsp all-purpose flour for every 1 tbsp cornstarch when you need a quick pantry substitute for thickening food
Starch gelatinization plays a pivotal role in thickening sauces and gravies. When it comes to thickening agents, cornstarch outperforms flour, as twice the amount of flour is necessary to achieve the same results as cornstarch. To prevent lumps, m...

A representative image of a creamy sauce thickening as it is stirred over a gas stovetop, with all-purpose flour ready nearby. Image credits: ChatGPT
Running out of cornstarch mid-recipe is a common enough kitchen problem that most cooks have a rough instinct for how to handle it: reach for flour instead. That instinct is correct, and it's backed by a specific ratio and a specific piece of food chemistry. According to a food-science review, "Starch gelatinization," published in the journal Advances in Food and Nutrition Research by researchers at the University of Nebraska-Lincoln, the thickening ability of both flour and cornstarch comes down to one mechanism: starch gelatinization, which occurs when starch granules swell, absorb water, and eventually burst as they're heated. Once you understand that a single reaction is doing the job in both cases, the swap stops being guesswork.Why cornstarch is the overachiever of the pantry
Cornstarch has some notable properties. Nearly 100% starch, no protein, fat, or fiber like wheat flour. According to an Institute of Food Science and Technology article, starch granules begin to swell at about 140°F, absorb about five times their own volume of liquid when the pot reaches 185°F, and break apart, releasing molecules that are responsible for thickening a sauce. Flour experiences the same kind of swell and burst, but has to be used about roughly twice as much because of the protein and fibre used to break down the flour. That's why the classic swap is made up of 2 tablespoons of flour and 1 tablespoon of cornstarch.
The 2:1 rule, decoded
A 2022 “7 Cornstarch Substitutes You Might Already Have in Your Kitchen,” guide from America's Test Kitchen states that mixing flour and cornstarch in a ratio of 2:1 is the best way to replace flour in soups and gravies, and warns that no flour should be added to a hot pot of food or it will clump into lumps almost immediately. Instead, add it to a small amount of cold water or fat, and then add the slurry to it, little by little, as it simmers.

Not gluten-free, flour is a non-starter for the increasing number of Americans who have to steer clear of gluten; cornstarch, tapioca starch, or arrowroot is the safer route there. Flour-thickened sauces also lose some of their thickening power the longer they're exposed to acidic ingredients like tomatoes, wine, or citrus, and to prolonged cooking or vigorous stirring in general; that's true of cornstarch too, though cornstarch tends to hold up somewhat longer under heat and agitation before it starts to break down. But when it comes to crunch, cornstarch shows its superior edge over anything fried: coat with flour, and it gets darker and soggy quickly in comparison to a flour coating consisting of pure starch; thus, time and temp adjustments will be necessary if substituting it for a crispy crust.

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