In 1943, researchers trying to fix America’s rubber crisis unexpectedly led to the creation of Silly Putty

Born from a wartime quest for rubber, Silly Putty emerged as an unexpected, stretchy, and bouncy material. Initially deemed unsuitable for industrial use due to its unpredictable nature, this peculiar polymer's unique properties eventually captiva...

A lab mistake during a rubber shortage discovered the strange material that became Silly Putty. Image credit - Wikimedia
Silly Putty has been described as a fun toy that could be purchased in eggs and desk drawers throughout America. However, it all started from research conducted in wartime laboratories. The scientists were looking for a solution to the problem of a shortage of rubber, which had become problematic for military needs and industry at that time.

The attempt to find an effective rubber replacement did not end up well, but resulted in a very unusual material that was stretchable, elastic, and even flowing at times. It became one of the most famous novelties in American history.

A rubber shortage due to war gave rise to research


With Japan occupying Southeast Asian countries rich in rubber, natural rubber became scarce for Americans during World War II. According to a report published by Carnegie Mellon University, tires, boots, various machines, medical items, and military supplies suffered from this shortage.

Chemists of the US Synthetic Rubber Program started researching different silicone substances in order to create a good alternative. One team, led by Earl Warrick, attempted to thicken polydimethylsiloxane fluids with the help of boric acid.

The scientists’ aim was rather practical and urgent – they needed a material similar in its properties to natural rubber. However, the result turned out to be quite peculiar. The material was capable of bouncing like a ball, elongating steadily, and suddenly snapping in two after rapid pulling. Thus, the material possessed both liquid-like and solid-like properties.
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According to the educational resource created by Carnegie Mellon University, initially, Silly Putty was intended to be used as an alternative to rubber in case of war. However, several years later, its commercial application appeared.

Why the material turned out to be inappropriate to be used as artificial rubber

It did not take long for researchers to figure out that the material would not suit the needs of the wartime industry. As a PDMS-based elastomer with abnormal viscoelastic behavior, Silly Putty would not be able to provide enough strength for any application. The material did not respond to pressure and stress in a predictable way. Slow elongation resulted in deformation. It broke when you pulled on it too quickly.

Later research on borosiloxane systems discovered that it was due to its dynamic molecular bonding structure that created such strange rheological properties. According to a PubMed article, these unique properties were the reason why Silly Putty had that bouncy and stretchable feature.
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While those features were undesirable during wartime for engineers who needed reliable materials, they would become their most appealing traits among the public later on.



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​Carnegine Mellon Institute fellows
Carnegine Mellon Institute fellows (from left) John Speier, Earl Warrick and Rob McGregor discuss a new product. Image credit - Carnegine Mellon Institute
The invention of Silly Putty is not as straightforward as many people think

There has never been an accepted inventor of Silly Putty. While James Wright is usually acknowledged as the inventor of this compound, Carnegie Mellon University reports that chemist Earl Warrick was also involved in inventing this rubberlike polymer and did related patent work in the 1940s.

Historians report that Warrick and his colleagues patented a process of treating dimethyl silicone polymer with boric oxide in 1943. A number of discoveries made during World War II period resulted from the massive research efforts carried out by many chemists, labs, and industry partners. The case of Silly Putty is one example of such research efforts.

The failed experiment turned into a cultural hit

Despite its ineffectiveness as a synthetic rubber, researchers and other lab visitors allegedly found its peculiar properties interesting enough. The substance bounced high, copied newspaper prints, could stretch, and broke when applied with rapid force. These unique properties kept it interesting for many years after its usefulness in the war ended.

Today, scientific literature continues to describe Silly Putty as a very important example of a material with unusual polymer properties and viscoelasticity. As scientists claim, the material attracts researchers due to its peculiarities under certain conditions.

At last, marketing people realized that the failed attempt to create rubber could be used commercially for amusement. Thus, the product turned into a popular item available in toy shops throughout America.

What makes the history of Silly Putty relevant today


Despite failing to resolve the U.S.’s wartime rubber problem, the initial discovery unveiled a substance with physical qualities never before seen. The scientists had been looking for one thing but stumbled upon something completely new.

This phenomenon has proven to be one of the most famous instances of accidental discovery in American scientific history. The ability of Silly Putty to stretch and bounce was not consciously designed by the chemists. Rather, it emerged from the unanticipated behavior of chemicals.

While now recognized as a plaything for kids, behind Silly Putty lies an important wartime saga of shortages, experimentation, and a laboratory fiasco that wouldn’t let go.
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