In 1869, Dmitri Mendeleev fell asleep while organizing chemical elements: and woke up with the periodic table

In the 1860s, Dmitri Mendeleev revolutionized chemistry by organizing elements into a periodic table. His audacious act of leaving empty spaces for undiscovered elements, and accurately predicting their properties, transformed chemistry from desc...

In 1869, Dmitri Mendeleev fell asleep while organizing chemical elements: and woke up with the periodic table
In the 1860s, chemistry was rife with isolated facts. Over sixty chemical elements had been discovered by scientists, yet there existed no system that described the connection between all of the elements. Scientists around Europe had been attempting to formulate an understanding of atomic weights, reactions, and common chemical properties in such a way that they fit together meaningfully. As noted by the Royal Society of Chemistry, although scientists had recognized the existence of periodicities in chemistry, nobody had yet found a successful way of organizing all of these elements into one consistent system. This is where Dmitri Mendeleev enters the story, as he was a professor in Saint Petersburg who was writing a textbook on chemistry.

However, the method used by Mendeleev proved rather physical in nature. The Science History Institute recorded that Mendeleev wrote down the characteristics of each element separately on individual cards, which he shuffled several times around his table while trying to establish a pattern. Mendeleev observed that when the elements were arranged according to their atomic weights, there were repeated chemical patterns. This pattern became the basis of what we now call the periodic law. As per later accounts mentioned by Britannica and the Royal Society of Chemistry, Mendeleev labored tirelessly over the pattern until he fell asleep at his table and had a vision of the desired result. This story about the dream is now one of the best-known stories in science. The experts advise that some elements may have been simplified, but what matters is that Mendeleev saw a pattern that revolutionized chemistry by transforming it from an amorphous collection of items to a structured field. But even more, there was one thing he did that many scientists were unwilling to do before him. He made deliberate holes in the periodic table because those elements had not yet been discovered.



How did the Empty Spaces Change Science Forever?

The most audacious aspect of the periodic table of Mendeleev, however, did not lie in its construction, but rather in its certainty. As Britannica and the Royal Society of Chemistry indicate, he left empty slots on his chart in anticipation of elements whose discovery seemed inevitable based on the repetition of the patterns. Not only that, but he also made accurate calculations regarding the properties of such elements based on estimates of their atomic masses, densities, and chemical characteristics. This occurred, for example, when he predicted the presence of an element he called eka-silicon in a time before germanium was discovered in 1886. Since then, whenever new elements were discovered and their chemical and physical characteristics proved to match Mendeleev's predictions, his reputation was further cemented. Gallium and scandium were examples of other elements he had foreseen. As the American Chemical Society describes it, his accurate forecasts about elements not yet discovered turned a useful model into proof of the laws of chemistry.

The predictive power of the table altered the way chemistry operates to this day. Prior to Mendeleev, science seemed more descriptive than analytical. Scientists could classify substances and chemical reactions; however, many of their connections appeared random and unexplained. Thanks to the periodic table, chemists were able to see how elements were connected systematically. Moreover, the periodic table helped them realize that any similarities found within different substances had underlying reasons and stemmed from the atomic structure. This significance became even more apparent when science progressed into the twentieth century and developed theories regarding atomic structure. Further research on atoms, electrons, atomic number, and quantum mechanics allowed the scientific community to learn why there was such a strong periodicity. However, amazingly enough, the table came up much earlier, long before anything was known about atomic structure.


Dmitri Mendeleev
Dmitri MendeleevImage Credit: Wikimedia Commons/Public Domain

Mendeleev’s Table Still Influences Everyday Life

In today's world, the periodic table is ubiquitous, which makes it hard to realize how groundbreaking it used to be at first. The periodic table now adorns laboratory walls and textbooks all around the globe, being regarded as something ordinary and trivial rather than a discovery that has forever changed our understanding of science. But virtually all areas of contemporary chemistry remain based on the periodic properties discovered by Mendeleev in 1869. As indicated by the United Nations Educational, Scientific, and Cultural Organization, as part of their International Year of the Periodic Table celebration, the periodic table helps in a variety of fields, including electronics, medicine, agriculture, and environmental science. The knowledge of how elements behave helps chemists to create drugs, batteries, semiconductors, and other industrial materials needed in the modern world.
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The personal life story of Mendeleev is also relevant due to its connection with the scientific process in general, which involves putting order into disorder. This scientist did not have computers and a clear understanding of atomic theory; rather, he had pages of handwritten notes with information about elements that needed to be systematized in an ordered way. This aspect makes this person’s story especially relevant. The picture of a scientist falling asleep at the desk and realizing later on some sort of logic in the mess represents the process of scientific discovery very well. Often, people do not make discoveries out of thin air but after a long period of frustration and repetition, when the mind works intensively on solving some issue. Mendeleev’s contribution to chemistry was significant because he understood that elements belonged to some bigger whole structure.
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